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I am currently taking anti-inflammatories (Naproxen 500 mg) for a nerve pain in my leg. Can I also take acetaminophen to relieve a headache?

Yes, you can take acetaminophen to help relieve a headache while taking anti-inflammatories like Naproxen. However, it is not recommended to take multiple anti-inflammatories at the same time (e.g. Advil/Motrin + Naproxen). If you have any other questions, feel free to ask.