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Is there a children's product (acetaminophen/ibuprofen) to relieve toothaches WITHOUT flavor/sugar?

Yes, there are children's pain relief products like acetaminophen and ibuprofen available without flavor or sugar added. One example is children's Advil™ in grape flavor, which can be given to children as young as 6 months old. It is often well-tolerated by children and can help relieve tooth pain.